UCLA/Getty Conservation Program

A graduate conservation training program focusing on the conservation of archaeological and ethnographic materials


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Powdery Paint Consolidation Part I: Setting up an Ultrasonic Humidifier and Nebulizer

…or more aptly titled “The trials and tribulations of how to set up this equipment and only get two seconds of a consolidation mist before it all goes wrong”.

And no, that isn’t too much of an exaggeration. As useful as the application of a consolidant mist is for the treatment of powdery or unbound paint, we have found that the set up of the equipment can be difficult, and getting it to actually work can be hit or miss. There seem to be a lot of components to the systems—with connectors and tubing providing areas for leaks and many locations where things can go wrong. Though some images or diagrams in the literature describe the “proper” set up, it still seems that the systems are a little tricky to set up and do not always work consistently (if at all!). We recently set up these misting systems for a lab the conservation program students undertook on the consolidation of powdery paint for the course on the Deterioration and Conservation of Organic Materials III (CAEM241), and we thought it might be helpful to share how we set up our equipment, some of our discoveries along the way, and the issues we encountered.

For those of you not familiar with this type of consolidation, in which the consolidant is atomized or aerosolized, it can be preferable to other methods of application because small quantities of consolidant can be applied as extremely fine particles in a controllable flow. This is especially helpful for paints that are unbound or underbound (such as matte, powdery paints often found on Oceanic and African artifacts), as it provides a low impact method of application. To achieve this, you can use an ultrasonic humidifier, aerosol generator, a nebulizer or some other type of equipment to create a mist that is then applied to the area of powdery paint you want to consolidate. Ultrasonic misting allows for very fine droplets (about 1-10 microns) to be delivered in an airstream saturated with solvent positioned close to the surface (therefore the solvent evaporates very minimally); this offers an advantage over pneumatic sprays, which may evaporate in the air before reaching the object, becoming too viscous to properly penetrate the paint (Michalski, et al. 1994).

powdery paint on wood

Detail of wooden object with powdery paint on the surface

Problems that are usually associated with consolidation of powdery pigments (darkening, glossy appearance, smearing), are often due to the fact that too much consolidant is being used at concentrations that are too high, while ultrasonic misting can avoid both of these problems. Misting requires the use of very dilute solutions, allowing for a weak consolidant to be applied to a relatively broad area. This form of application also allows the treatment to be carefully assessed as it progresses, so that the consolidation may be stopped before any noticeable darkening or other alterations to the surface occurs. As we will see, the use of the ultrasonic humidifier, the nebulizer or the aerosol generator involves a relatively complex set up, which can create a number of challenges.

And so the saga begins…
If your lab is lucky enough to have something like the AGS 2000 HS aerosol generator from Lascaux, then you don’t have to worry about any kind of set up. This piece of equipment is ready to use and does not require additional equipment or components (or “jerry-rigging”). However, the aerosol generator is expensive and it developed after conservators implemented alternative systems employing an ultrasonic humidifier or nebulizer to produce a mist for consolidation. For this particular class, we had the students work with the aerosol generator, but we also wanted them to use the other two systems since those would likely be the types they would encounter at other institutions or even have to set up themselves.

Elizabeth Drolet uses the AGS 2000 HS aerosol generator to consolidate powdery paint.

Elizabeth Drolet uses the aerosol generator to consolidate powdery paint.

The ultrasonic humidifier – The day starts off on somewhat of a high note
The first system we set up was with the ultrasonic humidifier. Luckily for us, there are some good published diagrams of how it needs to be assembled (Cavanaugh 2001 ; Dignard, et al. 1997). The system consists of an ultrasonic humidifier, an aquarium pump to provide pressurized air, an LDPE (low density polyethylene) bottle into which you place your consolidant, and tubing. This method is relatively inexpensive. You only need a household ultrasonic humidifier and an air pump or compressor. We used a small aquarium pump, the Optima Maxima A-806 pump with a rheostat, as our air source.

We cut two holes into the LDPE bottle, as illustrated in the diagrams from the referenced articles, and inserted two pieces of tubing, held in place with EVA (ethylene vinyl acetate) low melt, hot glue. One piece of tubing was connected to the aquarium pump and the other piece of tubing acted as the nozzle for the delivery of the consolidant. We wanted to create a fine tip at the end of the delivery tube for the application of the consolidant, so we cut the end off of a plastic disposable pipette and inserted it over the end of the tubing.

The LDPE bottle was positioned just above the oscillator of the humidifier and held in place using a small lab stand. We didn’t place the bottle directly on the oscillator because in the past contact with the oscillator caused the bottom of the bottle to melt. We then filled the humidifier reservoir with water.

Ultrasonic humidifier

Our ultrasonic humidifier set-up

Now it was time to add our consolidant. For initial set up and testing of the system we just used deionized water to act as our trial “consolidant”. When we added our “consolidant” to the LDPE bottle, we made sure that the level of the trial “consolidant” did not go above the water level of the reservoir.

So we set everything up, turned on the aquarium pump, then turned on the humidifier, and….SUCCESS!! We got mist!

Okay, okay, it wasn’t that easy. We left out some of the problems we encountered with setting it up.

  • Not all humidifiers are the same or seemed to work
    We had two humidifiers in the lab: a Holmes brand ultrasonic humidifier and a Sunbeam ultrasonic humidifier that we use for the Preservation Pencil. For some reason we could not get the Sunbeam humidifier to produce a mist using this set up, even though it works as a humidifier. We aren’t really sure why this happened. We did notice when looking at the two humidifiers that the oscillator and surrounding plastic disc of the Sunbeam humidifier is smaller in diameter than the one in the Holmes humidifier (1.7cm in diameter as opposed to the 4cm oscillator and surrounding plastic disc on the Holmes humidifier). For now our theory is that the smaller Sunbeam humidifier’s oscillator is not powerful enough to produce a mist, but we aren’t exactly sure what is going on.
  • The length of the tubing used to deliver your consolidant makes a difference
    If the consolidant delivery tube was too long, we did not seem to get any misting. We thought this could be because our aquarium pump was not powerful enough to push the air/mist through such a long tube. If the tube was too short, we would get more unwanted droplets of consolidant coming out of the nozzle, and in some cases these were pushed out of the tube with some force by the air pressure. The amount of air flowing through the tubing and the intensity of the oscillation also affected how much liquid consolidant was pushed through the end of the nozzle.  We found that adjusting the rheostat on both the aquarium pump and the humidifier helped mitigate this.

The nebulizer – Where things got frustrating and started to go wrong (and when Teflon tape became our best friend)

Feeling pretty confident from our successful set up of the ultrasonic humidifier, we started to work on putting together the nebulizer. It has fewer components to the system so we thought it should be a piece of cake—or not—as we were soon to learn.

For the application of a nebulizer for consolidation, some treatments have involved the use of a medical nebulizer (Grantham and Cummings 2002) which again, like the aerosol generator, comes ready to use. In our case we were going to assemble our own nebulizer system using a nebulizer cup (which is where you place the consolidant) and a source of compressed air (using the aquarium pump).

The nebulizer cups we bought have two openings: a side arm to attach the tubing for the air and a hole on the lid of the cup where we attach tubing to deliver the consolidant. We used some silicone tubing that came with the aquarium pump to connect the pump to the nebulizer’s side arm. We then used clear tubing and attached it to the opening on the top of the nebulizer using polypropylene connector/reducer nozzles purchased from a lab supplier. We once again cut the tip off of a plastic disposable pipette and inserted it at the end of the tubing as our nozzle.

Nebulizer

The nebulizer attached to the aquarium pump

With everything connected, we filled the nebulizer with water, turned on the aquarium pump and waited…and waited….and kept waiting…but there was no mist. We talked to a colleague (who had successfully used a nebulizer for mist consolidation) who said that we needed to make sure there were no air leaks anywhere. So we grabbed our Teflon tape and wrapped it everywhere there was a connection to ensure all the parts fit together tightly with no air leaks. She also mentioned that she filled the nebulizer cup half way with consolidant, which seemed to be the right amount to get the mist to form for her. So we filled our cups half way with deionized water, but still got nothing.

We then noticed that the solution in the cup did not seem to be aerosolizing or moving much at all and we could only feel a small amount of air coming out of the tube. We wondered if this was caused by the length of the tubing we were using, like with the ultrasonic humidifier, but shortening or lengthening the tubing either from the pump to the nebulizer or for solvent delivery did not make a difference.

Our next idea was that the aquarium pump we were using did not have enough pressure to produce a mist. The Optima Maxima A-806 pump works at a maximum pressure of 2.5 psi (pounds per square inch). We tried a compressor we had for our air brush which has an operating pressure of 20-40 psi. We connected the nebulizer to it, turned it on and immediately produced a mist!

Nebulizer and air brush compressor

The nebulizer connected to the air brush compressor (20-40 psi)

We noticed, however, that there was a very strong flow of air coming out of the delivery nozzle. When we tried to “consolidate” a facsimile with flaking paint, the air coming out of the nozzle blew the paint flakes off of the surface. The compressor seemed to be too powerful.  This meant we had to find a compressor that was stronger than the small aquarium pump but not too strong to blow the fragile paint off the surface of an object. We settled on a slighter larger aquarium pump with a psi of 4 (the Optima Maxima pump A-407) and that seemed to work well in producing a mist.

nebulizer with compressor and blown flakes

The nebulizer when attached to the air brush compressor produced too strong of an air flow which blew off flakes of paint from the facsimile tested.

In addition to the difficulties with trying to find the right air compressor to produce the mist, we also had some issues with the length of the consolidant delivery tube. We wanted the tube length of the delivery nozzle to be long so we would not have to hold the nebulizer cup in our hand while conducting the treatment and instead could leave it on the table. However, we found that if the tube was too long, no mist was produced. Therefore, we had to settle for a shorter tube length for the delivery nozzle, which meant holding the nebulizer cup over or right next to the object while consolidating it.

consolidating with nebulizer

Cindy Lee Scott tries out the nebulilzer. Because the tube for the delivery nozzle had to be short in order for the mist consolidation to work, the nebulizer cup had to be held close to the object (or over it) during treatment.

After a couple of days of setting up and trying to get the nebulizer and ultrasonic humidifier to work successfully with water, we were ready to try the mist consolidation on facsimiles with powdery paint, using actual consolidants. Stay tuned for part II of this post, which will discuss how those treatments went and the issues we encountered.

References

Cavanaugh, Jan.  2001.  The Feasibility of Ultrasonic Misting as an Inpainting Technique.  WAAC Newsletter.  Vol. 23, No. 1 (January).

Dignard, Carole, Robyn Douglas, Sherry Guild, Anne Maheux, and Wanda McWilliams. 1997. Ultrasonic Misting, Part 2, Treatment Applications. Journal of the American Institute for Conservation 36(2): 127-141.

Grantham, S. and A. Cummings. 2002. “Painted Japanese paper screens: the consolidation of paint layers on a paper substrate. In The broad spectrum: studies in the materials, techniques, and conservation of color on paper, eds. H.K. Stratis and B. Salvesen. London: Archetype Publications.

Michalski, Stefan, Carole Dignard, Lort van Handel, and David Arnold. 1994. The Ultrasonic Mister: Applications in the Consolidation of Powdery Paint on Wooden Artifacts. In Painted Wood: History and Conservation, Proceedings of a symposium organized by the Wooden Artifacts Group of the American Institute for Conservation of Historic and Artistic Works and the Foundation of the AIC, held at the Colonial Williamsburg Foundation, ed. V. Dorge and F. C. Howlett. Los Angeles: The Getty Conservation Institute, 1-18.

Dawn Lohnas (’12) , Vanessa Muros (Staff Research Associate) and Ellen Pearlstein (Assoc. Professor UCLA/Getty Program and Information Studies)

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Conservation program projects in 2010 issue of Backdirt

The latest issue of Backdirt, the annual magazine of the Cotsen Institute of Archaeology, highlights some of the projects undertaken in 2009-2010 by students and faculty of the UCLA/Getty Conservation Program.


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2010 ANAGPIC Papers are Published

Student papers from the 2010 ANAGPIC conference held at Queen’s University are now available online. Check out the following papers from UCLA/Getty Program students Nicole Ledoux, Cindy Lee Scott, and Elizabeth Drolet. Abstracts of the papers and links to the PDF version can be found below.

Congratulations to our students on the publication of their paper and all their hard work on these projects!

Treatment and Technical Study of a Lakota Beaded Hide
Nicole Ledoux

This paper discusses the conservation and technical study of a Lakota (est.) beaded hide object in very poor condition. The piece, whose original function is not known, was reported as collected in the late 19th or early 20th century by John Anderson, a photographer living on the Rosebud reservation in South Dakota. It was passed down through family lines until it was recently donated to the UCLA/Getty conservation program. At some point in its history, the piece suffered liquid damage that has drastically altered more than half of the hide area, causing darkening, embrittlement, fragmentation, and damage to the associated beadwork, including localized staining resulting in part from bead corrosion. In order to better understand these alterations and their implications for conservation treatment, a technical study has been undertaken that includes both morphological characterization and materials analysis of the hide and tannins. Continued work has included identification of bead composition and characterization of the various alteration products, as well as consultation with tribal and museum experts about original function and appropriate loss compensation. This object provides an interesting case study for investigating the deterioration of semi-tanned hide and the approach taken in treating such significantly altered material.

The Chemical Characterization and Removal of Lac Dye Staining on White-Ground Ceramics
Cindy Lee Scott and Elizabeth Drolet (UCLA/Getty), Rita Blaik, (UCLA Dept. of Materials Science and Engineering)

A late fifth century B.C. white-ground lekythos from the Antikensammlung Museum in Berlin was loaned to the J. Paul Getty Museum (JPGM) in 2006 to be re-restored and studied.  The vessel fragments were poorly assembled with crude shellac in the nineteenth century.  As a part of the conservation efforts at the Getty, the vase was disassembled by fuming in a solvent saturated environment of a 1:1 mixture of ethanol and acetone, which caused a pinkish-purple stain to develop.  Although  numerous materials and techniques were tested, an adequate method for removing the stain has not yet been found.

This paper builds upon the research conducted by conservators and conservation scientists at the JPGM-Department of Antiquities Conservation and the Los Angeles County Museum of Art (LACMA) and aims to characterize the nature of the chemical bond formed between the lac dye- a constituent of crude shellac- and the substrate of the white-ground.  The methodology is based on experimental and analytical testing on mock-up tiles and has two phases: first to replicate and characterize the staining and second, to perform cleaning trials using a variety of poulticing materials and organic solvents to adequately reduce or remove the staining without altering the white-ground surface.